Versatile Precursors for the Synthesis of Enynes and Enediynes

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Versatile Precursors for the Synthesis of Enynes and Enediynes

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Title: Versatile Precursors for the Synthesis of Enynes and Enediynes
Author: Myers, Andrew; Harrington, Philip M.; Finney, Nathaniel S.; Dragovich, Peter S.; Fuhry, Marry Ann M.; Alauddin, Mian M.

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Citation: Myers, Andrew G., Mian M. Alauddin, Mary Ann M. Fuhry, Peter S. Dragovich, Nathaniel S. Finney, and Philip M. Harrington. 1989. Versatile precursors for the synthesis of enynes and enediynes. Tetrahedron Letters 30(50): 6997-7000.
Access Status: At the direction of the depositing author this work is not currently accessible through DASH.
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Abstract: (Z)-Ethyl 2,3-dibromoproenoate, readily available in multigram quantities, undergoes selective replacement of the B-bromide in coupling reactions with trimethyl-silylacetylene to produce the (Z)-enyne 2. This product may be further elaborated to various functionalized enynes of defined geometry or may be coupled with a second acetylenic reactant to produce (Z)-enediynes.
Published Version: http://dx.doi.org/10.1016/S0040-4039(01)93407-0
Other Sources: http://www.chem.harvard.edu/groups/myers/pdf_publications/tetlet_1989_30_6997.pdf
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:3190375

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  • FAS Scholarly Articles [6463]
    Peer reviewed scholarly articles from the Faculty of Arts and Sciences of Harvard University
 
 

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