Structure of an 11-Membered Cyclic Silyl Enol Ether from Condensation of Methacrolein and a Pseudoephedrine-Derived O-Silyl Ketene N,O -Acetal

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Structure of an 11-Membered Cyclic Silyl Enol Ether from Condensation of Methacrolein and a Pseudoephedrine-Derived O-Silyl Ketene N,O -Acetal

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Title: Structure of an 11-Membered Cyclic Silyl Enol Ether from Condensation of Methacrolein and a Pseudoephedrine-Derived O-Silyl Ketene N,O -Acetal
Author: Myers, Andrew; Subramanian, Vijaya; Schaefer, William

Note: Order does not necessarily reflect citation order of authors.

Citation: Schaefer, William P., Vijaya Subramanian, and Andrew G. Myers. 1992. Structure of an 11-membered cyclic silyl enol ether from condensation of methacrolein and a pseudoephedrine-derived O-silyl ketene N,O -acetal. Acta Crystallographica Section C: Crystal Structure Communications C48: 2090-2092.
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Abstract: The title compound, (4S,5S,8R, IOZ)-2,2,5,6,8,10-hexamethyl-4-phenyl- 1,3-dioxa-6-aza-2-silacycloun-dec-10-en-7-one, crystallizes with two virtually identical molecules in the asymmetric unit, each with the same absolute configuration. Bond distances and angles are normal; the closest approaches across the ring between non-bonded atoms are all greater than 3.35 .A,. The amide and enol ether groups are planar to within +- 0.06 A.
Published Version: http://dx.doi.org/10.1107/S0108270192006851
Other Sources: http://www.chem.harvard.edu/groups/myers/publications.htm
Terms of Use: This article is made available under the terms and conditions applicable to Other Posted Material, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#LAA
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:3198690

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  • FAS Scholarly Articles [6463]
    Peer reviewed scholarly articles from the Faculty of Arts and Sciences of Harvard University
 
 

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