Nanomagnetic Control of Intersystem Crossing
| Title: | Nanomagnetic Control of Intersystem Crossing |
| Author: | Cohen, Adam Ezra |
| Citation: | Cohen, Adam E. 2009. Nanomagnetic control of intersystem crossing. The Journal of Physical Chemistry A 113(41): 11084-11092. |
| Access Status: | At the direction of the depositing author this work is not currently accessible through DASH. |
| Full Text & Related Files: |
Cohen_NanomagneticControl.pdf (1.017Mb; PDF) 
|
| Abstract: | A theory is presented for how magnetic nanostructures can catalyze intersystem crossing in molecular radical pairs. Magnetic field gradients near physically realistic nanostructures are strong enough to induce a relative reorientation of two electronic spins in <1 ns, overwhelming nuclear hyperfine coupling as a driver of intersystem crossing. Nanomagnetic control of intersystem crossing represents a form of heterogeneous catalysis that does not require molecular contact, but only short-range magnetic coupling. |
| Published Version: | doi:10.1021/jp907113p |
| Other Sources: | https://www2.lsdiv.harvard.edu/labs/cohen/Publications/CohenNanomagneticISC_JPCA.pdf |
| Citable link to this page: | http://nrs.harvard.edu/urn-3:HUL.InstRepos:4699752 |
This item appears in the following Collection(s)
-
FAS Scholarly Articles [5128]
Peer reviewed scholarly articles from the Faculty of Arts and Sciences of Harvard University
Contact administrator regarding this item (to report mistakes or request changes)
