Bimetallic Palladium Catalysis: Direct Observation of Pd(III)–Pd(III) Intermediates
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Bimetallic Palladium Catalysis: Direct Observation of Pd(III)–Pd(III) Intermediates
| Title: | Bimetallic Palladium Catalysis: Direct Observation of Pd(III)–Pd(III) Intermediates |
| Author: |
Ritter, Tobias; Powers, David C.; Geibel, Matthias A. L.; Klein, Johannes E. M. N.
Note: Order does not necessarily reflect citation order of authors. |
| Citation: | Powers, David C., Matthias A. L. Geibel, Johannes E. M. N. Klein, and Tobias Ritter. 2009. Bimetallic palladium catalysis: Direct observation of Pd(III)–Pd(III) intermediates. Journal of the American Chemical Society 131(47): 17050–17051. |
| Full Text & Related Files: |
JACS 2009, 131, 17050.pdf (629.7Kb; PDF) 
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| Abstract: | \(PhI(OAc)_2\) is a common oxidant for Pd-catalyzed C−H bond functionalizations. Mechanistic hypotheses since the 1960s have suggested a Pd(II)/Pd(IV) mechanism. Here we present evidence for the relevance of bimetallic Pd(III) complexes to catalysis. A bimetallic Pd(III) acetate was isolated and can afford product by bimetallic reductive elimination. |
| Published Version: | doi:10.1021/ja906935c |
| Other Sources: | http://www.ncbi.nlm.nih.gov/pubmed/19899740 |
| Terms of Use: | This article is made available under the terms and conditions applicable to Open Access Policy Articles, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#OAP |
| Citable link to this page: | http://nrs.harvard.edu/urn-3:HUL.InstRepos:8156526 |
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Peer reviewed scholarly articles from the Faculty of Arts and Sciences of Harvard University
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