Bimetallic Palladium Catalysis: Direct Observation of Pd(III)–Pd(III) Intermediates

DSpace/Manakin Repository

Bimetallic Palladium Catalysis: Direct Observation of Pd(III)–Pd(III) Intermediates

Citable link to this page

. . . . . .

Title: Bimetallic Palladium Catalysis: Direct Observation of Pd(III)–Pd(III) Intermediates
Author: Ritter, Tobias; Powers, David C.; Geibel, Matthias A. L.; Klein, Johannes E. M. N.

Note: Order does not necessarily reflect citation order of authors.

Citation: Powers, David C., Matthias A. L. Geibel, Johannes E. M. N. Klein, and Tobias Ritter. 2009. Bimetallic palladium catalysis: Direct observation of Pd(III)–Pd(III) intermediates. Journal of the American Chemical Society 131(47): 17050–17051.
Full Text & Related Files:
Abstract: \(PhI(OAc)_2\) is a common oxidant for Pd-catalyzed C−H bond functionalizations. Mechanistic hypotheses since the 1960s have suggested a Pd(II)/Pd(IV) mechanism. Here we present evidence for the relevance of bimetallic Pd(III) complexes to catalysis. A bimetallic Pd(III) acetate was isolated and can afford product by bimetallic reductive elimination.
Published Version: doi:10.1021/ja906935c
Other Sources: http://www.ncbi.nlm.nih.gov/pubmed/19899740
Terms of Use: This article is made available under the terms and conditions applicable to Open Access Policy Articles, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#OAP
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:8156526

Show full Dublin Core record

This item appears in the following Collection(s)

  • FAS Scholarly Articles [6885]
    Peer reviewed scholarly articles from the Faculty of Arts and Sciences of Harvard University
 
 

Search DASH


Advanced Search
 
 

Submitters