| dc.contributor.author | Powers, David C. | |
| dc.contributor.author | Geibel, Matthias A. L. | |
| dc.contributor.author | Klein, Johannes E. M. N. | |
| dc.contributor.author | Ritter, Tobias | |
| dc.date.accessioned | 2012-02-10T21:12:31Z | |
| dc.date.issued | 2009 | |
| dc.identifier.citation | Powers, David C., Matthias A. L. Geibel, Johannes E. M. N. Klein, and Tobias Ritter. 2009. Bimetallic palladium catalysis: Direct observation of Pd(III)–Pd(III) intermediates. Journal of the American Chemical Society 131(47): 17050–17051. | en_US |
| dc.identifier.issn | 0002-7863 | en_US |
| dc.identifier.issn | 1520-5126 | en_US |
| dc.identifier.uri | http://nrs.harvard.edu/urn-3:HUL.InstRepos:8156526 | |
| dc.description.abstract | \(PhI(OAc)_2\) is a common oxidant for Pd-catalyzed C−H bond functionalizations. Mechanistic hypotheses since the 1960s have suggested a Pd(II)/Pd(IV) mechanism. Here we present evidence for the relevance of bimetallic Pd(III) complexes to catalysis. A bimetallic Pd(III) acetate was isolated and can afford product by bimetallic reductive elimination. | en_US |
| dc.description.sponsorship | Chemistry and Chemical Biology | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.isversionof | doi:10.1021/ja906935c | en_US |
| dc.relation.hasversion | http://www.ncbi.nlm.nih.gov/pubmed/19899740 | en_US |
| dash.license | OAP | |
| dc.subject | catalysis | en_US |
| dc.subject | kinetics | en_US |
| dc.subject | palladium | en_US |
| dc.subject | chemistry | en_US |
| dc.title | Bimetallic Palladium Catalysis: Direct Observation of Pd(III)–Pd(III) Intermediates | en_US |
| dc.type | Journal Article | en_US |
| dc.description.version | Author's Original | en_US |
| dc.relation.journal | Journal of the American Chemical Society | en_US |
| dash.depositing.author | Ritter, Tobias | |
| dc.date.available | 2012-02-10T21:12:31Z | |
| dc.identifier.doi | 10.1021/ja906935c | * |
| dash.contributor.affiliated | Ritter, Tobias | |
