Browsing by Author "Scharf, Austin"
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Electronic Perturbations of Iron Dipyrrinato Complexes via Ligand β-Halogenation and meso -Fluoroarylation
Scharf, Austin Bennett; Betley, Theodore A (American Chemical Society (ACS), 2011)Systematic electronic variations were introduced into the monoanionic dipyrrinato ligand scaffold via halogenation of the pyrrolic β-positions and/or via the use of fluorinated aryl substituents in the ligand bridgehead ... -
First-Row Transition Metal Complexes of Dipyrrinato Ligands: Synthesis and Characterization
Scharf, Austin Bennett (2013-10-15)A library of variously-substituted dipyrrins and their first-row transition metal (Mn, Fe, Cu, Zn) complexes have been synthesized, and the effects of peripheral substituents on the spectroscopic, electrochemical, and ...