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Synthesis, Structure, and Reactivity of New Palladium(III) Complexes

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2014-06-06

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Campbell, Michael Glenn. 2014. Synthesis, Structure, and Reactivity of New Palladium(III) Complexes. Doctoral dissertation, Harvard University.

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Abstract

Palladium is one of the most common and versatile transition metals used in modern organometallic chemistry. The chemistry of palladium in its 0, +II, and +IV oxidation states is well-known; by comparison, the chemistry of palladium in its +III oxidation state is in its infancy. The work in this thesis involves the study of previously unknown Pd(III) complexes, including applications in materials chemistry and catalysis.

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Chemistry, Fluorination, Metal-Metal Bonding, Molecular Wires, Organometallics, Palladium

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