Publication: Synthesis and Redox Properties of Triiron Complexes Featuring Strong Fe-Fe Interactions
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Date
2011
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Wiley-Blackwell
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Zhao, Qinliang, and Theodore A. Betley. 2011. “Synthesis and Redox Properties of Triiron Complexes Featuring Strong Fe-Fe Interactions.” Angewandte Chemie International Edition 50, no. 3: 709–712.
Abstract
A modular hexadentate polyamide ligand directs the assembly of triiron complexes (see structure). Crystallographic studies reveal significant metal–metal bonding interactions, which are enhanced upon oxidation.
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Keywords
iron complexes, metal cluster, polyamide ligand, polynuclear complexes, redox reactions
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