# Polarized Raman Scattering Studies of Orientational Order in Uniaxial Liquid Crystalline Phases

 Title: Polarized Raman Scattering Studies of Orientational Order in Uniaxial Liquid Crystalline Phases Author: Jen, Shen; Clark, Noel A.; Pershan, Peter S.; Priestley, E. B. Note: Order does not necessarily reflect citation order of authors. Citation: Jen, Shen, Noel A. Clark, Peter S. Pershan, and E. B. Priestley. 1977. Polarized Raman scattering studies of orientational order in uniaxial liquid crystalline phases. Journal of Chemical Physics 66(10): 4635-4661. Full Text & Related Files: Jen_Polarized.pdf (2.114Mb; PDF) Abstract: The measurement of vibrational Raman depolarization ratios has been used to study molecular orientational order in uniaxial single domain nematic and smectic liquid crystal samples. This technique is demonstrated to obtain the same microscopic order parameter $$\langle P_2 \rangle =1/2 \langle 3 cos^2\theta −1 \rangle$$, where $$\theta$$ is the angle between a molecular long axis and the uniaxial direction, as other existing methods. In addition, the next higher moment of the orientational distribution function $$\langle P_4 \rangle=1/8 \langle 35 cos^4 \theta−30 cos^2 \theta+3 \rangle$$ has been measured for the first time. The physical basis, theoretical apparatus, and experimental methods necessary for the application of this technique are thoroughly detailed in this paper. Measurements are presented of the temperature dependence of $$\langle P_2 \rangle$$ and $$\langle P_4 \rangle$$ of N‐(p'‐butoxybenzylidene)‐p‐cyanoaniline (BBCA) dissolved in N‐(p'‐methoxybenzylidene)‐p‐cyanoaniline (MBBA) and of pure MBBA in the isotropic and nematic phases, and in the isotropic, nematic, smectic A, and smectic B phases of N‐(p'‐butoxybenzylidene)‐p‐n‐octylaniline (40.8). In the nematic phases the new quantitative information marks significant discrepancies with existing theories of nematic ordering. In the smectic phases the results show unambiguously the anticipated high degree of molecular orientational order. Published Version: doi:10.1063/1.433720 Terms of Use: This article is made available under the terms and conditions applicable to Other Posted Material, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#LAA Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:10361969 Downloads of this work: