# Tuning Light Absorption in Core/Shell Silicon Nanowire Photovoltaic Devices through Morphological Design

 Title: Tuning Light Absorption in Core/Shell Silicon Nanowire Photovoltaic Devices through Morphological Design Author: Kim, Sun-Kyung; Day, Robert Watson; Cahoon, James F.; Kempa, Thomas Jan; Song, Kyung-Deok; Park, Hong-Gyu; Lieber, Charles M. Note: Order does not necessarily reflect citation order of authors. Citation: Kim, Sun-Kyung, Robert Watson Day, James F. Cahoon, Thomas Jan Kempa, Kyung-Deok Song, Hong-Gyu Park, and Charles M. Lieber. 2012. Tuning light absorption in core/shell silicon nanowire photovoltaic devices through morphological design. Nano Letters 12(9): 4971–4976. Full Text & Related Files: tuning_light_absorption.pdf (1.649Mb; PDF) Abstract: Subwavelength diameter semiconductor nanowires can support optical resonances with anomalously large absorption cross sections, and thus tailoring these resonances to specific frequencies could enable a number of nanophotonic applications. Here, we report the design and synthesis of core/shell p-type/intrinsic/n-type (p/i/n) Si nanowires (NWs) with different sizes and cross-sectional morphologies as well as measurement and simulation of photocurrent spectra from single-NW devices fabricated from these NW building blocks. Approximately hexagonal cross-section p/i/n coaxial NWs of various diameters (170–380 nm) were controllably synthesized by changing the Au catalyst diameter, which determines core diameter, as well as shell deposition time, which determines shell thickness. Measured polarization-resolved photocurrent spectra exhibit well-defined diameter-dependent peaks. The corresponding external quantum efficiency (EQE) spectra calculated from these data show good quantitative agreement with finite-difference time-domain (FDTD) simulations and allow assignment of the observed peaks to Fabry–Perot, whispering-gallery, and complex high-order resonant absorption modes. This comparison revealed a systematic red-shift of equivalent modes as a function of increasing NW diameter and a progressive increase in the number of resonances. In addition, tuning shell synthetic conditions to enable enhanced growth on select facets yielded NWs with approximately rectangular cross sections; analysis of transmission electron microscopy and scanning electron microscopy images demonstrate that growth of the n-type shell at $$860^{\circ}C$$ in the presence of phosphine leads to enhanced relative Si growth rates on the four {113} facets. Notably, polarization-resolved photocurrent spectra demonstrate that at longer wavelengths the rectangular cross-section NWs have narrow and significantly larger amplitude peaks with respect to similar size hexagonal NWs. A rectangular NW with a diameter of 260 nm yields a dominant mode centered at 570 nm with near-unity EQE in the transverse-electric polarized spectrum. Quantitative comparisons with FDTD simulations demonstrate that these new peaks arise from cavity modes with high symmetry that conform to the cross-sectional morphology of the rectangular NW, resulting in low optical loss of the mode. The ability to modulate absorption with changes in nanoscale morphology by controlled synthesis represents a promising route for developing new photovoltaic and optoelectronic devices. Published Version: doi:10.1021/nl302578z Other Sources: http://www.ncbi.nlm.nih.gov/pubmed/22889329 Terms of Use: This article is made available under the terms and conditions applicable to Open Access Policy Articles, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#OAP Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:10397684 Downloads of this work:

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