Microtermolides A and B from Termite-Associated Streptomyces sp. and Structural Revision of Vinylamycin

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Microtermolides A and B from Termite-Associated Streptomyces sp. and Structural Revision of Vinylamycin

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Title: Microtermolides A and B from Termite-Associated Streptomyces sp. and Structural Revision of Vinylamycin
Author: Carr, Gavin; Poulsen, Michael; Klassen, Jonathan L.; Hou, Yanpeng; Wyche, Thomas P.; Bugni, Tim S.; Currie, Cameron R.; Clardy, Jon C.

Note: Order does not necessarily reflect citation order of authors.

Citation: Carr, Gavin, Michael Poulsen, Jonathan L. Klassen, Yanpeng Hou, Thomas P. Wyche, Tim S. Bugni, Cameron R. Currie, and Jon Clardy. 2012. Microtermolides A and B from termite-associated Streptomyces sp. and structural revision of vinylamycin. Organic Letters 14(11): 2822-2825.
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Abstract: Microtermolides A (1) and B (2) were isolated from a Streptomyces sp. strain associated with fungus-growing termites. The structures of 1 and 2 were determined by 1D- and 2D-NMR spectroscopy and high-resolution mass spectrometry. Structural elucidation of 1 led to the re-examination of the structure originally proposed for vinylamycin (3). Based on a comparison of predicted and experimental \(^1\)H and \(^{13}\)C NMR chemical shifts, we propose that vinylamycin’s structure be revised from 3 to 4.
Published Version: doi:10.1021/ol301043p
Other Sources: http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3365539/pdf/
Terms of Use: This article is made available under the terms and conditions applicable to Other Posted Material, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#LAA
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:10417533
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