Elucidation of the Cation−π Interaction in Small-Molecule Asymmetric Catalysis

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Elucidation of the Cation−π Interaction in Small-Molecule Asymmetric Catalysis

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Title: Elucidation of the Cation−π Interaction in Small-Molecule Asymmetric Catalysis
Author: Lin, Song
Citation: Lin, Song. 2013. Elucidation of the Cation−π Interaction in Small-Molecule Asymmetric Catalysis. Doctoral dissertation, Harvard University.
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Abstract: The cation&ndash;&pi; interaction has been long-established to play an important role in molecular recognition, supramolecular chemistry, and molecular biology. In contrast, its potential application in small-molecule catalysis, especially as a selectivity-determining factor in asymmetric synthesis has been overlooked until very recently. This dissertation begins with an extensive literature review on the state-of-the-art research on the application of cation&ndash;&pi; interactions in non-enzymatic catalysis of organic and organometallic transformations. The research in this field has been largely inspired and guided by the related biosynthetic systems incorporating the same type of interactions.</p>
Terms of Use: This article is made available under the terms and conditions applicable to Other Posted Material, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#LAA
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:11169771
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