The Rate of Charge Tunneling through Self-Assembled Monolayers Is Insensitive to Many Functional Group Substitutions

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The Rate of Charge Tunneling through Self-Assembled Monolayers Is Insensitive to Many Functional Group Substitutions

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Title: The Rate of Charge Tunneling through Self-Assembled Monolayers Is Insensitive to Many Functional Group Substitutions
Author: Yoon, Hyo Jae; Shapiro, Nathan D.; Park, Kyeng Min; Thuo, Martin M.; Soh, Siowling; Whitesides, George McClelland

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Citation: Yoon, Hyo Jae, Nathan D. Shapiro, Kyeng Min Park, Martin M. Thuo, Siowling Soh, and George M. Whitesides. 2012. The Rate of Charge Tunneling through Self-Assembled Monolayers Is Insensitive to Many Functional Group Substitutions. Angewandte Chemie International Edition 51, no. 19: 4658–4661.
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Abstract: Insensitivity: A series of molecules containing a common head group and body as well as structurally varied tail groups (-R) has been used in junctions with the structure Ag/S(CH2)4CONH(CH2)2R//Ga2O3/EGaIn to study the rates of charge transport by tunneling. Changing the structure of R over a range of common aliphatic, aromatic, and heteroaromatic organic groups was found to not significantly influence the rate of tunneling (see plots; the dashed lines represent calibration standards).
Published Version: doi:10.1002/anie.201201448
Terms of Use: This article is made available under the terms and conditions applicable to Open Access Policy Articles, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#OAP
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:11956909
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