Structural Characterization of Charcoal Exposed to High and Low pH: Implications for 14C Sample Preparation and Charcoal Preservation

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Structural Characterization of Charcoal Exposed to High and Low pH: Implications for 14C Sample Preparation and Charcoal Preservation

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Title: Structural Characterization of Charcoal Exposed to High and Low pH: Implications for 14C Sample Preparation and Charcoal Preservation
Author: Rebollo, N.; Cohen-Ofri, I.; Popovitz-Biro, R.; Bar-Yosef, Ofer; Meignen, L.; Goldberg, P.; Weiner, S.; Boaretto, E.

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Citation: Rebollo, N., I. Cohen-Ofri, R. Popovitz-Biro, O. Bar-Yosef, L. Meignen, P. Goldberg, S. Weiner, and E. Boaretto. 2008. Structural Characterization of Charcoal Exposed to High and Low pH: Implications for 14C Sample Preparation and Charcoal Preservation. Radiocarbon 50, no. 2: 289–307.
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Abstract: Chemical and structural similarities between poorly preserved charcoal and its contaminants, as well as low radiocarbon concentrations in old samples, complicate 14C age determinations. Here, we characterize 4 fossil charcoal samples from the late Middle Paleolithic and early Upper Paleolithic strata of Kebara Cave, Israel, with respect to the structural and chemical changes that occur when they are subjected to the acid-base-acid (ABA) treatment. Differential thermal analysis and TEM show that acid treatment disrupts the structure, whereas alkali treatment results in the reformation of molecular aggregates. The major changes are ascribed to the formation of salt bridges at high pH and the disruption of the graphite-like crystallites at low pH. Weight losses during the treatments are consistently greater for older samples, implying that they are less well preserved. Based on the changes observed in vitro due to pH fluctuations, various methods for removing contamination, as well as a mechanism for preferential preservation of charcoal in nature, are proposed.
Published Version: https://journals.uair.arizona.edu/index.php/radiocarbon/article/view/3729
Other Sources: http://www.academia.edu/5993442/Structural_characterization_of_charcoal_exposed_to_high_and_low_Ph_implications_for_C14_sample_preparation_and_charcoal_preservation
Terms of Use: This article is made available under the terms and conditions applicable to Other Posted Material, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#LAA
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:12242821
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