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dc.contributor.authorBoursalian, Gregory Bagrad
dc.contributor.authorNgai, Ming-Yu
dc.contributor.authorHojczyk, Katarzyna Natalia
dc.contributor.authorRitter, Tobias
dc.date.accessioned2014-06-17T16:15:34Z
dc.date.issued2013
dc.identifier.citationBoursalian, Gregory B., Ming-Yu Ngai, Katarzyna N. Hojczyk, and Tobias Ritter. 2013. Pd-Catalyzed Aryl C–H Imidation with Arene as the Limiting Reagent. Journal of the American Chemical Society 135, no. 36: 13278–13281.en_US
dc.identifier.issn0002-7863en_US
dc.identifier.issn1520-5126en_US
dc.identifier.urihttp://nrs.harvard.edu/urn-3:HUL.InstRepos:12330895
dc.description.abstractAn amine-N-oxide-ligated palladium complex, in conjunction with a silver cocatalyst, catalyzes imidation of arenes by the reagent N-fluorobenzenesulfonimide. The reaction enables imidation of a variety of arenes at or below room temperature, requires no coordinating directing group on the substrate, and gives synthetically useful yields with only 1 equiv of arene. Mechanistic data implicate an unusual mechanism devoid of commonly invoked organometallic intermediates: oxidation of the Pd catalyst occurs as the turnover-limiting step, while C–H bond functionalization occurs subsequently at a high oxidation state of the catalyst.en_US
dc.description.sponsorshipChemistry and Chemical Biologyen_US
dc.language.isoen_USen_US
dc.publisherAmerican Chemical Society (ACS)en_US
dc.relation.isversionofdoi:10.1021/ja4064926en_US
dc.relation.hasversionhttp://rittergroup.org/pdf/2013-13278j.pdfen_US
dash.licenseOAP
dc.titlePd-Catalyzed Aryl C–H Imidation with Arene as the Limiting Reagenten_US
dc.typeJournal Articleen_US
dc.description.versionAccepted Manuscripten_US
dc.relation.journalJournal of the American Chemical Societyen_US
dash.depositing.authorRitter, Tobias
dc.date.available2014-06-17T16:15:34Z
dc.identifier.doi10.1021/ja4064926*
workflow.legacycommentsFAR 2014en_US
dash.contributor.affiliatedHojczyk, Katarzyna Natalia
dash.contributor.affiliatedBoursalian, Gregory
dash.contributor.affiliatedRitter, Tobias


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