Palladium(III)-Catalyzed Fluorination of Arylboronic Acid Derivatives
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CitationMazzotti, Anthony R., Michael G. Campbell, Pingping Tang, Jennifer M. Murphy, and Tobias Ritter. 2013. Palladium(III)-Catalyzed Fluorination of Arylboronic Acid Derivatives. Journal of the American Chemical Society 135, no. 38: 14012–14015.
AbstractA practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated and characterized.
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