Polymer Amide as an Early Topology

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Polymer Amide as an Early Topology

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Title: Polymer Amide as an Early Topology
Author: McGeoch, Julie E. M.; McGeoch, Malcolm W.

Note: Order does not necessarily reflect citation order of authors.

Citation: McGeoch, Julie E. M., and Malcolm W. McGeoch. 2014. “Polymer Amide as an Early Topology.” PLoS ONE 9 (7): e103036. doi:10.1371/journal.pone.0103036. http://dx.doi.org/10.1371/journal.pone.0103036.
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Abstract: Hydrophobic polymer amide (HPA) could have been one of the first normal density materials to accrete in space. We present ab initio calculations of the energetics of amino acid polymerization via gas phase collisions. The initial hydrogen-bonded di-peptide is sufficiently stable to proceed in many cases via a transition state into a di-peptide with an associated bound water molecule of condensation. The energetics of polymerization are only favorable when the water remains bound. Further polymerization leads to a hydrophobic surface that is phase-separated from, but hydrogen bonded to, a small bulk water complex. The kinetics of the collision and subsequent polymerization are discussed for the low-density conditions of a molecular cloud. This polymer in the gas phase has the properties to make a topology, viz. hydrophobicity allowing phase separation from bulk water, capability to withstand large temperature ranges, versatility of form and charge separation. Its flexible tetrahedral carbon atoms that alternate with more rigid amide groups allow it to deform and reform in hazardous conditions and its density of hydrogen bonds provides adhesion that would support accretion to it of silicon and metal elements to form a stellar dust material.
Published Version: doi:10.1371/journal.pone.0103036
Other Sources: http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4105422/pdf/
Terms of Use: This article is made available under the terms and conditions applicable to Other Posted Material, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#LAA
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:12717452
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