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dc.contributor.authorHerrera, Felipe
dc.contributor.authorPeropadre, Borja
dc.contributor.authorPachon, Leonardo Augusto
dc.contributor.authorSaikin, Semion K.
dc.contributor.authorAspuru-Guzik, Alan
dc.date.accessioned2014-12-09T13:29:09Z
dc.date.issued2014
dc.identifier.citationHerrera, Felipe, Borja Peropadre, Leonardo Augusto Pachon, Semion K. Saikin, and Alán Aspuru-Guzik. 2014. “Quantum Nonlinear Optics with Polar J-Aggregates in Microcavities.” Journal of Physical Chemistry Letters 5 (21) (November 6): 3708–3715. doi:10.1021/jz501905h.en_US
dc.identifier.issn1948-7185en_US
dc.identifier.urihttp://nrs.harvard.edu/urn-3:HUL.InstRepos:13479132
dc.description.abstractWe predict that an ensemble of organic dye molecules with permanent electric dipole moments embedded in a microcavity can lead to strong optical nonlinearities at the single-photon level. The strong long-range electrostatic interaction between chromophores due to their permanent dipoles introduces the desired nonlinearity of the light–matter coupling in the microcavity. We develop a semiclassical model to obtain the absorption spectra of a weak probe field under the influence of strong exciton–photon coupling with the cavity field. Using realistic parameters, we demonstrate that a cavity field with an average photon number near unity can significantly modify the absorptive and dispersive response of the medium to a weak probe field at a different frequency. Finally, we show that the system is in the regime of cavity-induced transparency with a broad transparency window for dye dimers. We illustrate our findings using pseudoisocyanine chloride (PIC) J-aggregates in currently available optical microcavities.en_US
dc.description.sponsorshipEngineering and Applied Sciencesen_US
dc.language.isoen_USen_US
dc.publisherAmerican Chemical Societyen_US
dc.relation.isversionofdoi:10.1021/jz501905hen_US
dc.relation.hasversionhttp://arxiv.org/pdf/1409.1930v1.pdfen_US
dash.licenseOAP
dc.subjectJ-aggregatesen_US
dc.subjectoptical microcavityen_US
dc.subjectquantum nonlinear opticsen_US
dc.subjectcavity-QEDen_US
dc.subjectelectromagnetically induced transparencyen_US
dc.titleQuantum Nonlinear Optics with Polar J-Aggregates in Microcavitiesen_US
dc.typeJournal Articleen_US
dc.description.versionAccepted Manuscripten_US
dc.relation.journalJournal of Physical Chemistry Lettersen_US
dash.depositing.authorAspuru-Guzik, Alan
dc.date.available2014-12-09T13:29:09Z
dc.identifier.doi10.1021/jz501905h*
workflow.legacycommentsFLAG2. ArXiv file available - swap this for published version?en_US
dash.contributor.affiliatedPachon, Leonardo Augusto
dash.contributor.affiliatedAspuru-Guzik, Alan


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