dc.contributor.author | Furuya, Takeru | |
dc.contributor.author | Benitez, Diego | |
dc.contributor.author | Tkatchouk, Ekaterina | |
dc.contributor.author | Strom, Alexandra E. | |
dc.contributor.author | Tang, Pingping | |
dc.contributor.author | Goddard, William A. | |
dc.contributor.author | Ritter, Tobias | |
dc.date.accessioned | 2015-03-11T17:25:55Z | |
dc.date.issued | 2010 | |
dc.identifier.citation | Furuya, Takeru, Diego Benitez, Ekaterina Tkatchouk, Alexandra E. Strom, Pingping Tang, William A. Goddard, and Tobias Ritter. 2010. “Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides.” Journal of the American Chemical Society 132, no. 11: 3793–3807. | en_US |
dc.identifier.issn | 0002-7863 | en_US |
dc.identifier.uri | http://nrs.harvard.edu/urn-3:HUL.InstRepos:14117748 | |
dc.description.abstract | The first systematic mechanism study of C−F reductive elimination from a transition metal complex is described. C−F bond formation from three different Pd(IV) fluoride complexes was mechanistically evaluated. The experimental data suggest that reductive elimination occurs from cationic Pd(IV) fluoride complexes via a dissociative mechanism. The ancillary pyridyl-sulfonamide ligand plays a crucial role for C−F reductive elimination, likely due to a κ3 coordination mode, in which an oxygen atom of the sulfonyl group coordinates to Pd. The pyridyl-sulfonamide can support Pd(IV) and has the appropriate geometry and electronic structure to induce reductive elimination. | en_US |
dc.description.sponsorship | Chemistry and Chemical Biology | en_US |
dc.language.iso | en_US | en_US |
dc.publisher | American Chemical Society (ACS) | en_US |
dc.relation.isversionof | doi:10.1021/ja909371t | en_US |
dash.license | OAP | |
dc.title | Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides | en_US |
dc.type | Journal Article | en_US |
dc.description.version | Accepted Manuscript | en_US |
dc.relation.journal | Journal of the American Chemical Society | en_US |
dash.depositing.author | Ritter, Tobias | |
dc.date.available | 2015-03-11T17:25:55Z | |
dc.identifier.doi | 10.1021/ja909371t | * |
dash.contributor.affiliated | Ritter, Tobias | |