Browsing FAS Scholarly Articles by Keyword "forming reductive elimination"

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    • Bimetallic Redox Synergy in Oxidative Palladium Catalysis 

      Powers, David Charles; Ritter, Tobias (American Chemical Society, 2012)
      Polynuclear transition metal complexes, which are embedded in the active sites of many metalloenzymes, are responsible for effecting a diverse array of oxidation reactions in nature. The range of chemical transformations ...

    • Connecting Binuclear Pd(III) and Mononuclear Pd(IV) Chemistry by Pd–Pd Bond Cleavage 

      Powers, David Charles; Lee, Eunsung; Ariafard, Alireza; Sanford, Melanie S.; Yates, Brian F.; Canty, Allan J.; Ritter, Tobias (American Chemical Society, 2012)
      Oxidation of binuclear Pd(II) complexes with PhICl\(_2\) or PhI(OAc)\(_2\) has previously been shown to afford binuclear Pd(III) complexes featuring a Pd–Pd bond. In contrast, oxidation of binuclear Pd(II) complexes with ...