Transition-State Model for Entropy-Limited Freezing
View/ Open
Published Version
http://www.mrs.org/s_mrs/sec.asp?CID=1727&DID=38980Metadata
Show full item recordCitation
Aziz, Michael J., P. S. Peercy, Michael O. Thompson, and Jeff Y. Tsao. 1987. Transition-State model for entropy-limited freezing. Materials Research Society Symposia Proceedings 74: 117-122.Abstract
A brief review is given of transition-state theory, both for the case of unimolecular reactions in the gas phase, and for reactions in condensed phases. An argument is made that, within the context of this theory, heterogeneous freezing in Si is limited to rates much lower than collision rates by the difference between the entropies of the solid and the liquid.Terms of Use
This article is made available under the terms and conditions applicable to Other Posted Material, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#LAACitable link to this page
http://nrs.harvard.edu/urn-3:HUL.InstRepos:2848641
Collections
- FAS Scholarly Articles [18256]
Contact administrator regarding this item (to report mistakes or request changes)