Potential energy curves for the interaction of Ag(5s) and Ag(5p) with noble gas atoms

DSpace/Manakin Repository

Potential energy curves for the interaction of Ag(5s) and Ag(5p) with noble gas atoms

Citable link to this page

 

 
Title: Potential energy curves for the interaction of Ag(5s) and Ag(5p) with noble gas atoms
Author: Loreau, J.; Sadeghpour, Hossein R.; Dalgarno, Alexander

Note: Order does not necessarily reflect citation order of authors.

Citation: Loreau, J., H. R. Sadeghpour, and A. Dalgarno. 2013. “Potential Energy Curves for the Interaction of Ag(5s) and Ag(5p) with Noble Gas Atoms.” The Journal of Chemical Physics 138 (8) (February 28): 084301. doi:10.1063/1.4790586.
Full Text & Related Files:
Abstract: We investigate the interaction of ground and excited states of a silver atom with noble gases (NG), including helium. Born-Oppenheimer potential energy curves are calculated with quantum chemistry methods and spin-orbit effects in the excited states are included by assuming a spin-orbit splitting independent of the internuclear distance. We compare our results with experimentally available spectroscopic data, as well as with previous calculations. Because of strong spin-orbit interactions, excited Ag-NG potential energy curves cannot be fitted to Morse-like potentials. We find that the labeling of the observed vibrational levels has to be shifted by one unit.
Published Version: doi:dx.doi.org/10.1063/1.4790586
Other Sources: https://arxiv.org/abs/1301.4575
Terms of Use: This article is made available under the terms and conditions applicable to Other Posted Material, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#LAA
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:30403726
Downloads of this work:

Show full Dublin Core record

This item appears in the following Collection(s)

 
 

Search DASH


Advanced Search
 
 

Submitters