Proposed Structure of the Neocarzinostatin Chromophore-Methyl Thioglycolate Adduct; A Mechanism for the Nucleophilic Activation of Neocarzinostatin

Myers, Andrew

View/Open

(420.3Kb)

Access Status

Full text of the requested work is not available in DASH at this time ("restricted access"). For more information on restricted deposits, see our FAQ.

Citation

Myers, Andrew G. 1987. Proposed structure of the neocarzinostatin chromophore-methyl thioglycolate adduct; A mechanism for the nucleophilic activation of neocarzinostatin. Tetrahedron Letters 28(39): 4493-4496.

Abstract

Structure 1 is proposed to represent the product of reaction of methyl thioglycolate with the neocarzinostatin chromophore. A mechanism for the formation of 1 is presented which provides a rationale for the nucleophilic activation of neocarzinostatin.