Surface Structure of Liquid Bi and Sn: An X-Ray Reflectivity Study

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Surface Structure of Liquid Bi and Sn: An X-Ray Reflectivity Study

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dc.contributor.author Pershan, Peter S.
dc.contributor.author Stoltz, S. E.
dc.contributor.author Shpyrko, Oleg G.
dc.contributor.author Deutsch, Moshe
dc.contributor.author Balagurusamy, Venkatachalapathy S. K.
dc.contributor.author Meron, Mati
dc.contributor.author Lin, Binhua
dc.contributor.author Streitel, Reinhard
dc.date.accessioned 2010-02-18T18:22:23Z
dc.date.issued 2009
dc.identifier.citation Pershan, Peter S., S. E. Stoltz, Oleg G. Shpyrko, Moshe Deutsch, Venkatachalapathy S. K. Balagurusamy, Mati Meron, Binhua Lin, and Reinhard Streite. 2009. Surface structure of liquid Bi and Sn: An x-ray reflectivity study. Physical Review B 79(11): 115417. en_US
dc.identifier.issn 1098-0121 en_US
dc.identifier.uri http://nrs.harvard.edu/urn-3:HUL.InstRepos:3659692
dc.description.abstract X-ray reflectivity measurements of the liquid Bi surface are presented and analyzed together with previous liquid Sn results. Published measurements on liquid Ga, In, and K all exhibit a single strong maximum at a wave-vector transfer of the order of the reciprocal of an atomic-diameter, due to surface-induced layering. In contrast, both Sn and Bi exhibit—in addition—a weak broad peak at much smaller wave-vector transfers. This feature is an unambiguous signature of an enhanced electron density in the near-surface region. Possible ways of modeling this enhancement are presented. Once the different surface-roughening effects of thermal capillary waves are accounted for, the surface structure factors of Sn and Bi are remarkably similar. The principal difference between the two is that the depth of the layering below the surface is more than ∼40% larger for Bi than for Sn. This is considerably larger than the ratio of their covalent radii which is only ∼10%. No theoretical explanation can be offered at this time for the surface structure difference between Sn and Bi and other elemental liquid metals studied to date: Ga, In, and K. en_US
dc.description.sponsorship Engineering and Applied Sciences en_US
dc.language.iso en_US en_US
dc.publisher American Physical Society en_US
dc.relation.isversionof doi:10.1103/PhysRevB.79.115417 en_US
dc.relation.hasversion http://liquids.seas.harvard.edu/peter/2009.pdf/Bi.pdf en_US
dash.license META_ONLY
dc.title Surface Structure of Liquid Bi and Sn: An X-Ray Reflectivity Study en_US
dc.type Journal Article en_US
dc.description.version Version of Record en_US
dc.relation.journal Physical Review B en_US
dash.depositing.author Pershan, Peter S.
dash.embargo.until 10000-01-01

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