Enantioselective Synthesis of (+)-Cephalostatin 1

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Enantioselective Synthesis of (+)-Cephalostatin 1

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Title: Enantioselective Synthesis of (+)-Cephalostatin 1
Author: Fortner, Kevin; Kato, Darryl; Tanaka, Yoshiki; Shair, Matthew David

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Citation: Fortner, Kevin, Darryl Kato, Yoshiki Tanaka, Matthew David Shair. 2010. Enantioselective Synthesis of (+)-Cephalostatin 1. Journal of the American Chemical Society 132(1): 275-280.
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Abstract: This Article describes an enantioselective synthesis of cephalostatin 1. Key steps of this synthesis are a unique methyl group selective allylic oxidation, directed C−H hydroxylation of a sterol at C12, Au(I)-catalyzed 5-endo-dig cyclization, and a kinetic spiroketalization.
Published Version: doi:10.1021/ja906996c
Terms of Use: This article is made available under the terms and conditions applicable to Open Access Policy Articles, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#OAP
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:7982718
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