Bimetallic Palladium Catalysis: Direct Observation of Pd(III)–Pd(III) Intermediates
Powers, David C.
Geibel, Matthias A. L.
Klein, Johannes E. M. N.
MetadataShow full item record
CitationPowers, David C., Matthias A. L. Geibel, Johannes E. M. N. Klein, and Tobias Ritter. 2009. Bimetallic palladium catalysis: Direct observation of Pd(III)–Pd(III) intermediates. Journal of the American Chemical Society 131(47): 17050–17051.
Abstract\(PhI(OAc)_2\) is a common oxidant for Pd-catalyzed C−H bond functionalizations. Mechanistic hypotheses since the 1960s have suggested a Pd(II)/Pd(IV) mechanism. Here we present evidence for the relevance of bimetallic Pd(III) complexes to catalysis. A bimetallic Pd(III) acetate was isolated and can afford product by bimetallic reductive elimination.
Citable link to this pagehttp://nrs.harvard.edu/urn-3:HUL.InstRepos:8156526
- FAS Scholarly Articles 
Contact administrator regarding this item (to report mistakes or request changes)