A Dinuclear Palladium Catalyst for \(\alpha\)-Hydroxylation of Carbonyls with \(O_2\)

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A Dinuclear Palladium Catalyst for \(\alpha\)-Hydroxylation of Carbonyls with \(O_2\)

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Title: A Dinuclear Palladium Catalyst for \(\alpha\)-Hydroxylation of Carbonyls with \(O_2\)
Author: Chuang, Gary Jing; Wang, Weike; Lee, Eunsung; Ritter, Tobias

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Citation: Chuang, Gary Jing, Weike Wang, Eunsung Lee, and Tobias Ritter. 2011. A dinuclear palladium catalyst for \(\alpha\)-hydroxylation of carbonyls with \(O_2\). Journal of the American Chemical Society 133(6), 1760–1762.
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Abstract: A chemo- and regioselective \(\alpha\)-hydroxylation reaction of carbonyl compounds with molecular oxygen as oxidant is reported. The hydroxylation reaction is catalyzed by a dinuclear Pd(II) complex, which functions as an oxygen transfer catalyst, reminiscent of an oxygenase. The development of this oxidation reaction was inspired by discovery and mechanism evaluation of previously unknown Pd(III)−Pd(III) complexes.
Published Version: doi:10.1021/ja108396k
Other Sources: http://www.ncbi.nlm.nih.gov/pubmed/21247109
Terms of Use: This article is made available under the terms and conditions applicable to Open Access Policy Articles, as set forth at http://nrs.harvard.edu/urn-3:HUL.InstRepos:dash.current.terms-of-use#OAP
Citable link to this page: http://nrs.harvard.edu/urn-3:HUL.InstRepos:8182916
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