Chiral Sulfinamide/Achiral Sulfonic Acid Cocatalyzed Enantioselective Protonation of Enol Silanes
Beck, Elizabeth M.
Hyde, Alan M.Note: Order does not necessarily reflect citation order of authors.
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CitationBeck, Elizabeth M., Alan M. Hyde, and Eric N. Jacbosen. 2011. Chiral sulfinamide/achiral sulfonic acid cocatalyzed enantioselective protonation of enol silanes. Organic Letters 13(16): 4260-4263.
AbstractThe application of chiral sulfinamides and achiral sulfonic acids as a co-catalyst system for enantioselective protonation reactions is described. Structurally simple, easily accessible sulfinamides were found to induce moderate-to-high eeʼs in the formation of 2-aryl-substituted cycloalkanones from the corresponding trimethylsilyl enol ethers.
Citable link to this pagehttp://nrs.harvard.edu/urn-3:HUL.InstRepos:8737993
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