Lukin, MikhailHuan, Yan Qi2026-07-0720262026-05-142026Huan, Yan Qi. 2026. Nuclear Spin Memories for Silicon-Vacancy Quantum Network Nodes. Doctoral Dissertation, Harvard University Graduate School of Arts and Sciences.32578565https://dash.harvard.edu/handle/1/42744036Quantum networks will enable the transmission of quantum information over long distances, allowing us to link quantum computers for applications such as quantum cryptography, astronomical interferometry, and blind quantum computing. The silicon-vacancy center in diamond has emerged as a promising scalable solid-state platform capable of efficiently interfacing its electron spin with photons for long-range communication. This thesis investigates two long-lived nuclear spin qubits as quantum memories to significantly expand the quantum state storage and processing capabilities of this networking node. First, we demonstrate that selective isotope implantation gives a deterministic 29Si high-fidelity nuclear memory with coherence times over two seconds, enabling its integration into a two-node quantum network through 35 km of optical fiber deployed through the Boston metropolitan area. Next, we explore the control of a nearby 13C nuclear spin robust against repeated readouts and resets of the electron networking qubit, and utilize it to show a quadratic rate enhancement for entanglement swapping between two incoming photonic qubits. Together, these results advance our three-qubit node toward realistic operation as a quantum repeater to boost entanglement rates in a long-range network.application/pdfenQuantum physicsThesis or Dissertation2026-07-070000-0002-6505-7150