Sheberla, DennisSun, LeiForsythe, Martin Blood ZwirnerEr, SuleymanWade, Casey R.Brozek, Carl K.Aspuru-Guzik, AlanDincă, Mircea2017-07-132014Sheberla, Dennis, Lei Sun, Martin A. Blood-Forsythe, Süleyman Er, Casey R. Wade, Carl K. Brozek, Alán Aspuru-Guzik, and Mircea Dincă. 2014. “High Electrical Conductivity in Ni\(_3\)(2,3,6,7,10,11-Hexaiminotriphenylene)\(_2\), a Semiconducting Metal–Organic Graphene Analogue.” Journal of the American Chemical Society 136 (25) (June 25): 8859–8862. doi:10.1021/ja502765n.0002-7863http://nrs.harvard.edu/urn-3:HUL.InstRepos:33439107Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni_3(HITP)_2(HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal−organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S·cm−1, respectively, both records for MOFs and among the best for any coordination polymer.en-USJournal Article10.1021/ja502765n