Stauber, Julia M.Müller, PeterDai, YizheWu, GangNocera, DanielCummins, Christopher C.2017-07-202016Stauber, Julia M., Peter Müller, Yizhe Dai, Gang Wu, Daniel G. Nocera, and Christopher C. Cummins. 2016. “Multi-electron reactivity of a cofacial di-tin(II) cryptand: partial reduction of sulfur and selenium and reversible generation of S3.” Chem. Sci. 7 (12): 6928–6933. doi:10.1039/c6sc01754a.2041-6520http://nrs.harvard.edu/urn-3:HUL.InstRepos:33468944Cofacial bimetallic tin(II) ([Sn2(mBDCA-5t)]2−, 1) and lead(II) ([Pb2(mBDCA-5t)]2−, 2) complexes have been prepared by hexadeprotonation of hexacarboxamide cryptand mBDCA-5t-H6 together with double Sn(II) or Pb(II) insertion. Reaction of 1 with elemental sulfur or selenium generates di-tin polychalcogenide complexes containing μ-E and bridging μ-E5 ligands where E = S or Se, and the Sn(II) centers have both been oxidized to Sn(IV). Solution and solid-state UV-Vis spectra of [(μ-S5)Sn2(μ-S)(mBDCA-5t)]2− (4) indicate that the complex acts reversibly as a source of S3˙− in DMF solution with a Keq = 0.012 ± 0.002. Reductive removal of all six chalcogen atoms is achieved through treatment of [(μ-E5)Sn2(μ-E)(mBDCA-5t)]2− with PR3 (R = tBu, Ph, OiPr) to produce six equiv. of the corresponding EPR3 compound with regeneration of di-tin(II) cryptand complex 1.en-USJournal Article2017-05-1120162017-07-2010.1039/C6SC01754A