Browsing FAS Scholarly Articles by Author "Eames, Emily V."

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    • Metal Atom Lability in Polynuclear Complexes 

      Eames, Emily V.; Hernandez sanchez, Raul; Betley, Theodore A (American Chemical Society (ACS), 2013)
      The asymmetric oxidation product [(PhL)Fe3(μ-Cl)]2 [PhLH6 = MeC(CH2NHPh-o-NHPh)3], where each trinuclear core is comprised of an oxidized diiron unit [Fe2]5+ and an isolated trigonal pyramidal ferrous site, reacts with ...

    • Modulation of magnetic behavior via ligand-field effects in the trigonal clusters (PhL)Fe3L*3 (L* = thf, py, PMe2Ph) 

      Eames, Emily V.; Harris, T. David; Betley, Theodore A (Royal Society of Chemistry (RSC), 2012)
      Utilizing a hexadentate ligand platform, a series of trinuclear iron clusters (PhL)Fe3L*3 (PhLH6 1⁄4 MeC (CH2NPh-o-NPh)3; L* 1⁄4 tetrahydrofuran (1), pyridine (2), PMePh2 (3)) has been prepared. The phenyl substituents on ...

    • Site-Isolated Redox Reactivity in a Trinuclear Iron Complex 

      Eames, Emily V.; Betley, Theodore A (American Chemical Society (ACS), 2012)
      The symmetric, high-spin triiron complex (PhL)Fe3(thf)3 reacts with mild chemical oxidants (e.g., Ph3CX, I2) to afford an asymmetric core where one iron ion bears the halide ligand (PhL)Fe3X(L), and the hexadentate (PhL = ...