Person:

Qi, Chunhua

We present Submillimeter Array observations of H2CO and N2H+ emission in the disks around the T Tauri star TW Hya and the Herbig Ae star HD 163296 at 2"-6" resolution and discuss the distribution of these species with respect to CO freeze-out. The H2CO and N2H+ emission toward HD 163296 does not peak at the continuum emission center that marks the stellar position but is instead significantly offset. Using a previously developed model for the physical structure of this disk, we show that the H2CO observations are reproduced if H2CO is present predominantly in the cold outer disk regions. A model where H2CO is present only beyond the CO snow line (estimated at a radius of 160 AU) matches the observations well. We also show that the average H2CO excitation temperature, calculated from two transitions of H2CO observed in these two disks and a larger sample of disks around T Tauri stars in the DISCS (the Disk Imaging Survey of Chemistry with SMA) program, is consistent with the CO freeze-out temperature of 20 K. In addition, we show that N2H+ and H2CO line fluxes in disks are strongly correlated, indicative of co-formation of these species across the sample. Taken together, these results imply that H2CO and N2H+ are generally present in disks only at low temperatures where CO depletes onto grains, consistent with fast destruction of N2H+ by gas-phase CO, and in situ formation of H2CO through hydrogenation of CO ice. In this scenario H2CO, CH3OH and N2H+ emission in disks should appear as rings with the inner edge at the CO midplane snow line. This prediction can be tested directly using observations from ALMA with higher resolution and better sensitivity.

We report the first detection of c-C3H2 in a circumstellar disk. The c-C3H2 J = 6-5 line (217.882 GHz) is detected and imaged through Atacama Large Millimeter Array (ALMA) Science Verification observations toward the disk around the Herbig Ae star HD 163296 at 0.''8 resolution. The emission is consistent with that arising from a Keplerian rotating disk. Two additional c-C3H2 transitions are also tentatively detected, bolstering the identification of this species, but with insufficient signal-to-noise ratio to constrain the spatial distribution. Using a previously developed model for the physical structure of this disk, we fit a radial power-law distribution model to the c-C3H2 6-5 emission and find that c-C3H2 is present in a ring structure from an inner radius of about 30 AU to an outer radius of about 165 AU. The column density is estimated to be 1012-1013 cm–2. The clear detection and intriguing ring structure suggest that c-C3H2 has the potential to become a useful probe of radiation penetration in disks.

Planets form in the disks around young stars. Their formation efficiency and composition are intimately linked to the protoplanetary disk locations of “snow lines” of abundant volatiles. We present chemical imaging of the carbon monoxide (CO) snow line in the disk around TW Hya, an analog of the solar nebula, using high spatial and spectral resolution Atacama Large Millimeter/Submillimeter Array observations of diazenylium (N2H+), a reactive ion present in large abundance only where CO is frozen out. The N2H+ emission is distributed in a large ring, with an inner radius that matches CO snow line model predictions. The extracted CO snow line radius of ∼30 astronomical units helps to assess models of the formation dynamics of the solar system, when combined with measurements of the bulk composition of planets and comets.

Observations of comets and asteroids show that the Solar Nebula that spawned our planetary system was rich in water and organic molecules. Bombardment brought these organics to the young Earth's surface, seeding its early chemistry. Unlike asteroids, comets preserve a nearly pristine record of the Solar Nebula composition. The presence of cyanides in comets, including 0.01% of methyl cyanide (CH3CN) with respect to water, is of special interest because of the importance of C-N bonds for abiotic amino acid synthesis. Comet-like compositions of simple and complex volatiles are found in protostars, and can be readily explained by a combination of gas-phase chemistry to form e.g. HCN and an active ice-phase chemistry on grain surfaces that advances complexity[3]. Simple volatiles, including water and HCN, have been detected previously in Solar Nebula analogues - protoplanetary disks around young stars - indicating that they survive disk formation or are reformed in situ. It has been hitherto unclear whether the same holds for more complex organic molecules outside of the Solar Nebula, since recent observations show a dramatic change in the chemistry at the boundary between nascent envelopes and young disks due to accretion shocks[8]. Here we report the detection of CH3CN (and HCN and HC3N) in the protoplanetary disk around the young star MWC 480. We find abundance ratios of these N-bearing organics in the gas-phase similar to comets, which suggests an even higher relative abundance of complex cyanides in the disk ice. This implies that complex organics accompany simpler volatiles in protoplanetary disks, and that the rich organic chemistry of the Solar Nebula was not unique.

We have used the Submillimeter Array to image, at ~1farcs5 resolution, C2H $N=3\to 2$ emission from the circumstellar disk orbiting the nearby (D = 54 pc), ~8 Myr-old, ~0.8 ${{M}_{\odot }}$ classical T Tauri star TW Hya. The SMA imaging reveals that the C2H emission exhibits a ring-like morphology. Based on a model in which the C2H column density follows a truncated radial power-law distribution, we find that the inner edge of the ring lies at ~45 AU, and that the ring extends to at least ~120 AU. Comparison with previous (single-dish) observations of C2H $N=4\to 3$ emission indicates that the C2H molecules are subthermally excited and, hence, that the emission arises from the relatively warm ($T\gtrsim 40$ K), tenuous ($n\ll {{10}^{7}}$ cm−3) upper atmosphere of the disk. Based on these results and comparisons of the SMA C2H map with previous submillimeter and scattered-light imaging, we propose that the C2H emission most likely traces particularly efficient photo-destruction of small grains and/or photodesorption and photodissociation of hydrocarbons derived from grain ice mantles in the surface layers of the outer disk. The presence of a C2H ring in the TW Hya disk hence likely serves as a marker of dust grain processing and radial and vertical grain size segregation within the disk.

In a protoplanetary disk, a combination of thermal and non-thermal desorption processes regulate where volatiles are liberated from icy grain mantles into the gas phase. Non-thermal desorption should result in volatile-enriched gas in disk-regions where complete freeze-out is otherwise expected. We present Atacama Large Millimeter/Submillimeter Array observations of the disk around the young star IM Lup in 1.4 mm continuum, C18O 2–1, H13CO+ 3–2 and DCO+ 3–2 emission at ~0farcs5 resolution. The images of these dust and gas tracers are clearly resolved. The DCO+ line exhibits a striking pair of concentric rings of emission that peak at radii of ~0farcs6 and 2'' (~90 and 300 AU, respectively). Based on disk chemistry model comparison, the inner DCO+ ring is associated with the balance of CO freeze-out and thermal desorption due to a radial decrease in disk temperature. The outer DCO+ ring is explained by non-thermal desorption of CO ice in the low-column-density outer disk, repopulating the disk midplane with cold CO gas. The CO gas then reacts with abundant H2D+ to form the observed DCO+ outer ring. These observations demonstrate that spatially resolved DCO+ emission can be used to trace otherwise hidden cold gas reservoirs in the outmost disk regions, opening a new window onto their chemistry and kinematics.

The condensation fronts (snow lines) of H2O, CO, and other abundant volatiles in the midplane of a protoplanetary disk affect several aspects of planet formation. Locating the CO snow line, where the CO gas column density is expected to drop substantially, based solely on CO emission profiles, is challenging. This has prompted an exploration of chemical signatures of CO freeze-out. We present ALMA Cycle 1 observations of the N2H+ J = 3−2 and DCO+ J = 4−3 emission lines toward the disk around the Herbig Ae star HD 163296 at ~0farcs5 (60 AU) resolution, and evaluate their utility as tracers of the CO snow line location. The N2H+ emission is distributed in a ring with an inner radius at 90 AU, corresponding to a midplane temperature of 25 K. This result is consistent with a new analysis of optically thin C18O data, which implies a sharp drop in CO abundance at 90 AU. Thus N2H+ appears to be a robust tracer of the midplane CO snow line. The DCO+ emission also has a ring morphology, but neither the inner nor the outer radius coincide with the CO snow line location of 90 AU, indicative of a complex relationship between DCO+ emission and CO freeze-out in the disk midplane. Compared to TW Hya, CO freezes out at a higher temperature in the disk around HD 163296 (25 versus 17 K in the TW Hya disk), perhaps due to different ice compositions. This highlights the importance of actually measuring the CO snow line location, rather than assuming a constant CO freeze-out temperature for all disks.

The deuterium enrichment of molecules is sensitive to their formation environment. Constraining patterns of deuterium chemistry in protoplanetary disks is therefore useful for probing how material is inherited or reprocessed throughout the stages of star and planet formation. We present ALMA observations at ∼ 0.6 00 resolution of DCO+, H13CO+, DCN, and H13CN in the full disks around T Tauri stars AS 209 and IM Lup, in the transition disks around T Tauri stars V4046 Sgr and LkCa 15, and in the full disks around Herbig Ae stars MWC 480 and HD 163296. We also present ALMA observations of HCN in the IM Lup disk. DCN, DCO+, and H13CO+ are detected in all disks, and H13CN in all but the IM Lup disk. We find efficient deuterium fractionation for the sample, with estimates of disk-averaged DCO+/HCO+ and DCN/HCN abundance ratios ranging from ∼0.02–0.06 and ∼0.005–0.08, respectively, which is comparable to values reported for other interstellar environments. The relative distributions of DCN and DCO+ vary between disks, suggesting that multiple formation pathways may be needed to explain the diverse emission morphologies. In addition, gaps and rings observed in both H13CO+ and DCO+ emission provide new evidence that DCO+ bears a complex relationship with the location of the midplane CO snowline.

H2CO is one of the most readily detected organic molecules in protoplanetary disks. Yet its distribution and dominant formation pathway(s) remain largely unconstrained. To address these issues, we present ALMA observations of two H2CO lines (${3}{12}\mbox{--}{2}{11}$ and ${5}{15}\mbox{--}{4}{14}$) at 0farcs5 (~30 au) spatial resolution toward the disk around the nearby T Tauri star TW Hya. Emission from both lines is spatially resolved, showing a central depression, a peak at 0farcs4 radius, and a radial decline at larger radii with a bump at ~1'', near the millimeter continuum edge. We adopt a physical model for the disk and use toy models to explore the radial and vertical H2CO abundance structure. We find that the observed emission implies the presence of at least two distinct H2CO gas reservoirs: (1) a warm and unresolved inner component (<10 au), and (2) an outer component that extends from ~15 au to beyond the millimeter continuum edge. The outer component is further constrained by the line ratio to arise in a more elevated disk layer at larger radii. The inferred H2CO abundance structure agrees well with disk chemistry models, which predict efficient H2CO gas-phase formation close to the star, and cold H2CO grain surface formation, through H additions to condensed CO, followed by non-thermal desorption in the outer disk. The implied presence of active grain surface chemistry in the TW Hya disk is consistent with the recent detection of CH3OH emission, and suggests that more complex organic molecules are formed in disks, as well.