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Forsythe, Martin Blood Zwirner

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Martin Blood Zwirner

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Forsythe, Martin Blood Zwirner

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Author's Publications: search.filters.isAuthorOfPublication.9350ef8b-28ba-41f0-bd5a-4238c03cb085Author: search.filters.author.Brozek, Carl K.

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    High Electrical Conductivity in Ni(_3)(2,3,6,7,10,11-hexaiminotriphenylene)(_2), a Semiconducting Metal–Organic Graphene Analogue

    (American Chemical Society (ACS), 2014) Sheberla, Dennis; Sun, Lei; Forsythe, Martin Blood Zwirner; Er, Suleyman; Wade, Casey R.; Brozek, Carl K.; Aspuru-Guzik, Alan; Dincă, Mircea

    Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni_3(HITP)_2(HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal−organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S·cm−1, respectively, both records for MOFs and among the best for any coordination polymer.

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    High Electrical Conductivity in Ni 3 (2,3,6,7,10,11-hexaiminotriphenylene) 2 , a Semiconducting Metal–Organic Graphene Analogue

    (American Chemical Society (ACS), 2014) Sheberla, Dennis; Sun, Leizhi; Forsythe, Martin Blood Zwirner; Er, Suleyman; Wade, Casey R.; Brozek, Carl K.; Aspuru-Guzik, Alan; Dincă, Mircea

    Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni3(HITP)2 (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metalorganic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 Scm -1 and 40 Scm -1, respectively, both records for MOFs and among the best for any coordination polymer.