Detection of HCN and diverse redox chemistry in the plume of Enceladus

Abstract

The \textit{Cassini} spacecraft observed that Saturn’s moon Enceladus possesses a series of jets erupting from its South Polar Terrain. Previous studies of in situ data collected by \textit{Cassini}’s Ion and Neutral Mass Spectrometer (INMS) have identified H$_2$O, CO$_2$, CH$_4$, NH$_3$, and H$_2$ within the plume of ejected material. Identification of minor species in the plume remains an ongoing challenge, owing to the large number of possible combinations that can be used to fit the INMS data. Here, we present the detection of several new compounds of strong importance to the habitability of Enceladus, including HCN, C$_2$H$_2$, C$_3$H$_6$, and C$_2$H$_6$. Our analyses of the low velocity INMS data, coupled with our detailed statistical framework, enable discrimination between previously ambiguous species in the plume by alleviating the effects of high dimensional model fitting. Together with plausible mineralogical catalysts and redox gradients derived from surface radiolysis, these compounds could potentially support extant microbial communities or drive complex organic synthesis leading to the origin of life.