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Synthesis of GaNxAs1-x thin films by pulsed laser melting and rapid thermal annealing of N+-implanted GaAs

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2003

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American Institute of Physics
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Yu, Kin Man, Wladek Walukiewicz, Michael A. Scarpulla, Oscar D. Dubon, Jr., Jay Wu, Jacek Jasinski, Zuzanna Liliental-Weber, J. W. Beeman, Manoj R. Pillai, and Michael J. Aziz. Synthesis of GaN x As 1-x thin films by pulsed laser melting and rapid thermal annealing of N +-implanted GaAs. 2003. Journal of Applied Physics 94(2): 1043-1049.

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We present a systematic investigation on the formation of the highly mismatched alloy GaN<sub>x</sub>As<sub>1–x</sub> using N<sup>+</sup>-implantation followed by a combination of pulsed laser melting and rapid thermal annealing. Thin films of GaN<sub>x</sub>As<sub>1–x</sub> with x as high as 0.016 and an activation efficiency of the implanted N up to 50% have been synthesized with structural and optical properties comparable to films grown by epitaxial deposition techniques with similar substitutional N content. The effects of N<sup>+</sup> implantation dose, laser energy fluence, and rapid thermal annealing temperature on the N incorporation as well as optical and structural properties of the GaN<sub>x</sub>As<sub>1–x</sub> films are discussed.

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