Publication: C-H Bond Amination from a Ferrous Dipyrromethene Complex
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Date
2009
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American Chemical Society
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King, Evan R., and Theodore A. Betley. 2009. C-H bond amination from a ferrous dipyrromethene complex. Inorganic Chemistry 48(6): 2361-2363.
Abstract
In this Communication, we report an intramolecular C-H bond amination reaction of a dipyrromethene ferrous complex with organic azides. Monitoring of the spectral changes (variable temperature NMR and UV-vis) of the FeII complex reveals no buildup of an intermediate during conversion of the starting material into the nitrene-inserted product. The rate-determining step appears to be azide addition to the 14-electron FeII complex, hinting at the potential that these and related platforms may have to effect atom and group-transfer processes.
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