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Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes

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JACS 2009, 131, 12915.pdf (800.05 KB)

Date

2009

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10.1021/ja9048493

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American Chemical Society
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Wu, Jessica Y., Benoît Moreau, and Tobias Ritter. 2009. Iron-catalyzed 1,4-hydroboration of 1,3-dienes. Journal of the American Chemical Society 131(36): 12915–12917.

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Abstract

A chemo-, regio-, and stereoselective iron-catalyzed 1,4-hydroboration of dienes that affords γ-disubstituted allylboranes has been developed. 1,4-Hydroboration of 2-substituted dienes forms allylborane products with (E)-trisubstituted double bonds exclusively.

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http://www.ncbi.nlm.nih.gov/pubmed/19702262

Keywords

chemistry, boron compounds, alkadienes, catalysis, iron, molecular structure

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This article is made available under the terms and conditions applicable to Open Access Policy Articles (OAP), as set forth at Terms of Service

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http://nrs.harvard.edu/urn-3:HUL.InstRepos:8156525

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