Publication: Silver-Mediated Trifluoromethoxylation of Aryl Stannanes and Arylboronic Acids
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Date
2011
Published Version
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American Chemical Society
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Citation
Huang, Chenghong, Theresa Liang, Shinji Harada, Eunsung Lee, and Tobias Ritter. 2011. Silver-mediated trifluoromethoxylation of aryl stannanes and arylboronic acids. Journal of the American Chemical Society 133(34): 13308–13310.
Abstract
A silver-mediated cross-coupling of trifluoromethoxide with aryl stannanes and arylboronic acids to give aryl trifluoromethyl ethers is reported. This is the first report of a transition-metal-mediated (C_{aryl}–OCF_3) bond formation.
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Keywords
ethers, chemistry, boronic acids, fluorinated hydrocarbons, silver, tin compounds
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