Publication: Expanded redox accessibility via ligand substitution in an octahedral Fe6Br6 cluster
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Date
2011
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Royal Society of Chemistry (RSC)
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Harris, T. David, Qinliang Zhao, Raúl Hernández Sánchez, and Theodore A. Betley. 2011. “Expanded Redox Accessibility via Ligand Substitution in an Octahedral Fe6Br6 Cluster.” Chemical Communications 47, no. 22: 6344-6346.
Abstract
Oxidation of the nominally all-ferrous hexanuclear cluster (HL)2Fe6 with six equivalents of ferrocenium in the presence of bromide ions results in a six-electron oxidation of the Fe6 core to afford the nominally all-ferric cluster (HL)2Fe6Br6. The hexabromide cluster is also structurally characterized in a 4+ core oxidation state. A structural comparison of these two clusters provides an insight into the Fe6 core electronic structure.
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