Publication: Radiative transition probabilities of the 1s2p2P2 and 1s2p2D2 states of the lithium isoelectronic sequence
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1977
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American Physical Society (APS)
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Fox, J. L., and A. Dalgarno. 1977. “Radiative Transition Probabilities of the1s2p2P2and1s2p2D2states of the Lithium Isoelectronic Sequence.” Physical Review A 16 (1) (July 1): 283–288. doi:10.1103/physreva.16.283. http://dx.doi.org/10.1103/PhysRevA.16.283.
Abstract
A Z-expansion procedure is used to obtain eigenvalues and eigenfunctions for the 1s22p2Po, 1s2p2 2P, and 1s2p2 2D states of the lithium sequence. Expansions in inverse powers of the nuclear charge Z are obtained also for the dipole-matrix elements and oscillator strengths of the 1s22p2Po-1s2p2 2P and 1s22p 2Po=1s2p2 2D transitions, valid for Z>3. A separate calculation was performed for lithium. The calculated transition probabilities agree with the Hartree-Fock values of Gabriel for large Z, but there are considerable discrepancies with the experimental data.
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