Publication: Palladium(III)-Catalyzed Fluorination of Arylboronic Acid Derivatives
Loading...
Open/View Files
Date
2013
Published Version
Journal Title
Journal ISSN
Volume Title
Publisher
American Chemical Society (ACS)
The Harvard community has made this article openly available. Please share how this access benefits you.
Citation
Mazzotti, Anthony R., Michael G. Campbell, Pingping Tang, Jennifer M. Murphy, and Tobias Ritter. 2013. Palladium(III)-Catalyzed Fluorination of Arylboronic Acid Derivatives. Journal of the American Chemical Society 135, no. 38: 14012–14015.
Abstract
A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated and characterized.
Description
Other Available Sources
Research Data
Keywords
Terms of Use
This article is made available under the terms and conditions applicable to Open Access Policy Articles (OAP), as set forth at Terms of Service