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Mazzotti, Anthony Renato

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Mazzotti

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Anthony Renato

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Mazzotti, Anthony Renato

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Author's Publications: search.filters.isAuthorOfPublication.e0cf69f4-916f-423e-8940-ff7f8a8b8a30Author: search.filters.author.Tang, PingpingAuthor: search.filters.author.Murphy, JenniferAuthor: search.filters.author.Ritter, TobiasAuthor: search.filters.author.Campbell, Michael GlennItem Type: PublicationHas files: Yes

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    Palladium(III)-Catalyzed Fluorination of Arylboronic Acid Derivatives

    (American Chemical Society (ACS), 2013) Mazzotti, Anthony Renato; Campbell, Michael Glenn; Tang, Pingping; Murphy, Jennifer; Ritter, Tobias

    A practical, palladium-catalyzed synthesis of aryl fluorides from arylboronic acid derivatives is presented. The reaction is operationally simple and amenable to multigram-scale synthesis. Evaluation of the reaction mechanism suggests a single-electron-transfer pathway, involving a Pd(III) intermediate that has been isolated and characterized.