Browsing FAS Scholarly Articles by Author "Smaltz, Daniel Jonathan"
Now showing items 1-1 of 1
-
Diastereoselective Additions of Allylmetal Reagents to Free and Protectedsyn-?,?-Dihydroxyketones Enable Efficient Synthetic Routes to Methyl Trioxacarcinoside A
Smaltz, Daniel Jonathan; Svenda, Jakub; Myers, Andrew G. (American Chemical Society (ACS), 2012)Two routes to the 2,6-dideoxysugar methyl trioxacarcinoside A are described. Each was enabled by an apparent α-chelation-controlled addition of an allylmetal reagent to a ketone substrate containing a free α-hydroxyl group ...