Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes

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Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes

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Title: Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes
Author: Ritter, Tobias; Moreau, Benoît; Wu, Jessica Y.

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Citation: Wu, Jessica Y., Benoît Moreau, and Tobias Ritter. 2009. Iron-catalyzed 1,4-hydroboration of 1,3-dienes. Journal of the American Chemical Society 131(36): 12915–12917.
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Abstract: A chemo-, regio-, and stereoselective iron-catalyzed 1,4-hydroboration of dienes that affords γ-disubstituted allylboranes has been developed. 1,4-Hydroboration of 2-substituted dienes forms allylborane products with (E)-trisubstituted double bonds exclusively.
Published Version: doi:10.1021/ja9048493
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