| dc.contributor.author | Fortner, Kevin | |
| dc.contributor.author | Kato, Darryl | |
| dc.contributor.author | Tanaka, Yoshiki | |
| dc.contributor.author | Shair, Matthew David | |
| dc.date.accessioned | 2012-01-19T20:07:22Z | |
| dc.date.issued | 2010 | |
| dc.identifier.citation | Fortner, Kevin, Darryl Kato, Yoshiki Tanaka, Matthew David Shair. 2010. Enantioselective Synthesis of (+)-Cephalostatin 1. Journal of the American Chemical Society 132(1): 275-280. | en_US |
| dc.identifier.issn | 0002-7863 | en_US |
| dc.identifier.uri | http://nrs.harvard.edu/urn-3:HUL.InstRepos:7982718 | |
| dc.description.abstract | This Article describes an enantioselective synthesis of cephalostatin 1. Key steps of this synthesis are a unique methyl group selective allylic oxidation, directed C−H hydroxylation of a sterol at C12, Au(I)-catalyzed 5-endo-dig cyclization, and a kinetic spiroketalization. | en_US |
| dc.description.sponsorship | Chemistry and Chemical Biology | en_US |
| dc.language.iso | en_US | en_US |
| dc.publisher | American Chemical Society | en_US |
| dc.relation.isversionof | doi:10.1021/ja906996c | en_US |
| dash.license | OAP | |
| dc.subject | natural product | en_US |
| dc.subject | total synthesis | en_US |
| dc.subject | antiproliferative | en_US |
| dc.subject | cephalostatin | en_US |
| dc.title | Enantioselective Synthesis of (+)-Cephalostatin 1 | en_US |
| dc.type | Journal Article | en_US |
| dc.description.version | Author's Original | en_US |
| dc.relation.journal | Journal- American Chemical Society | en_US |
| dash.depositing.author | Shair, Matthew David | |
| dc.date.available | 2012-01-19T20:07:22Z | |
| dc.identifier.doi | 10.1021/ja906996c | * |
| dash.contributor.affiliated | Shair, Matthew | |
